A convenient synthesis of a Ru(bpy)3-based catenane-type triad and its incorporation into a protein scaffold

Yi Zhen Hu; Shinya Tsukiji; Seiji Shinkai; Itaru Hamachi

doi:10.1246/cl.1999.517

A convenient synthesis of a Ru(bpy)₃-based catenane-type triad and its incorporation into a protein scaffold

Yi Zhen Hu, Shinya Tsukiji, Seiji Shinkai, Itaru Hamachi

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

A catenated heme cofactor consisting of a donor (protoheme), a sensitizer (Ru(2,2'-bipyridine)₃) and an acceptor (cyclobis(paraquat-p-phenylene) was prepared by stepwise coordination, followed by iron-insersion. Reconstitution of apomyoglobin with this cofactor afforded a protein-based, noncovalently-1 inked photosynthetic triad.

Original language	English
Pages (from-to)	517-518
Number of pages	2
Journal	Chemistry Letters
Issue number	6
DOIs	https://doi.org/10.1246/cl.1999.517
Publication status	Published - 1999
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.1999.517

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abstract = "A catenated heme cofactor consisting of a donor (protoheme), a sensitizer (Ru(2,2'-bipyridine)3) and an acceptor (cyclobis(paraquat-p-phenylene) was prepared by stepwise coordination, followed by iron-insersion. Reconstitution of apomyoglobin with this cofactor afforded a protein-based, noncovalently-1 inked photosynthetic triad.",

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AU - Tsukiji, Shinya

AU - Shinkai, Seiji

AU - Hamachi, Itaru

PY - 1999

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A convenient synthesis of a Ru(bpy)₃-based catenane-type triad and its incorporation into a protein scaffold

Abstract

All Science Journal Classification (ASJC) codes

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