A cationic diruthenium amidinate, [(η5-C5Me 5)Ru(μ2-i-PrN=C(Me)Ni-Pr)Ru(η5-C 5Me5)]+, as an efficient catalyst for the atom-transfer radical reactions

Yukihiro Motoyama; Mitsuru Gondo; Satoshi Masuda; Yuya Iwashita; Hideo Nagashima

doi:10.1246/cl.2004.442

A cationic diruthenium amidinate, [(η⁵-C₅Me ₅)Ru(μ₂-i-PrN=C(Me)Ni-Pr)Ru(η⁵-C ₅Me₅)]⁺, as an efficient catalyst for the atom-transfer radical reactions

Yukihiro Motoyama, Mitsuru Gondo, Satoshi Masuda, Yuya Iwashita, Hideo Nagashima

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

A cationic diruthenium amidinate, [(η⁵-C₅Me ₅)Ru(μ₂-i-PrN=C(Me)Ni-Pr)Ru(η⁵-C ₅Me₅)]⁺, is generated by treatment of (η⁵-C₅Me₅)Ru(μ₂-i-PrN=C(Me) Ni-Pr)Ru(Cl)(η⁵-C₅Me₅) (3a) with NaPF ₆ or other metal salts of weakly coordinating anions, which is active towards catalytic atom transfer radical cyclization of N-allyl trichloroacetamides and related reactions.

Original language	English
Pages (from-to)	442-443
Number of pages	2
Journal	Chemistry Letters
Volume	33
Issue number	4
DOIs	https://doi.org/10.1246/cl.2004.442
Publication status	Published - Apr 5 2004

All Science Journal Classification (ASJC) codes

Chemistry(all)

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title = "A cationic diruthenium amidinate, [(η5-C5Me 5)Ru(μ2-i-PrN=C(Me)Ni-Pr)Ru(η5-C 5Me5)]+, as an efficient catalyst for the atom-transfer radical reactions",

abstract = "A cationic diruthenium amidinate, [(η5-C5Me 5)Ru(μ2-i-PrN=C(Me)Ni-Pr)Ru(η5-C 5Me5)]+, is generated by treatment of (η5-C5Me5)Ru(μ2-i-PrN=C(Me) Ni-Pr)Ru(Cl)(η5-C5Me5) (3a) with NaPF 6 or other metal salts of weakly coordinating anions, which is active towards catalytic atom transfer radical cyclization of N-allyl trichloroacetamides and related reactions.",

author = "Yukihiro Motoyama and Mitsuru Gondo and Satoshi Masuda and Yuya Iwashita and Hideo Nagashima",

year = "2004",

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doi = "10.1246/cl.2004.442",

language = "English",

volume = "33",

pages = "442--443",

journal = "Chemistry Letters",

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T1 - A cationic diruthenium amidinate, [(η5-C5Me 5)Ru(μ2-i-PrN=C(Me)Ni-Pr)Ru(η5-C 5Me5)]+, as an efficient catalyst for the atom-transfer radical reactions

AU - Motoyama, Yukihiro

AU - Gondo, Mitsuru

AU - Masuda, Satoshi

AU - Iwashita, Yuya

AU - Nagashima, Hideo

PY - 2004/4/5

Y1 - 2004/4/5

N2 - A cationic diruthenium amidinate, [(η5-C5Me 5)Ru(μ2-i-PrN=C(Me)Ni-Pr)Ru(η5-C 5Me5)]+, is generated by treatment of (η5-C5Me5)Ru(μ2-i-PrN=C(Me) Ni-Pr)Ru(Cl)(η5-C5Me5) (3a) with NaPF 6 or other metal salts of weakly coordinating anions, which is active towards catalytic atom transfer radical cyclization of N-allyl trichloroacetamides and related reactions.

AB - A cationic diruthenium amidinate, [(η5-C5Me 5)Ru(μ2-i-PrN=C(Me)Ni-Pr)Ru(η5-C 5Me5)]+, is generated by treatment of (η5-C5Me5)Ru(μ2-i-PrN=C(Me) Ni-Pr)Ru(Cl)(η5-C5Me5) (3a) with NaPF 6 or other metal salts of weakly coordinating anions, which is active towards catalytic atom transfer radical cyclization of N-allyl trichloroacetamides and related reactions.

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ER -

A cationic diruthenium amidinate, [(η⁵-C₅Me ₅)Ru(μ₂-i-PrN=C(Me)Ni-Pr)Ru(η⁵-C ₅Me₅)]⁺, as an efficient catalyst for the atom-transfer radical reactions

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