A carbon material as a strong protonic acid

Michikazu Hara; Takemi Yoshida; Atsushi Takagaki; Tsuyoshi Takata; Junko N. Kondo; Shigenobu Hayashi; Kazunari Domen

doi:10.1002/anie.200453947

A carbon material as a strong protonic acid

Michikazu Hara
, Takemi Yoshida
, Atsushi Takagaki
, Tsuyoshi Takata
, Junko N. Kondo
, Shigenobu Hayashi
, Kazunari Domen

Research output: Contribution to journal › Article › peer-review

609 Citations (Scopus)

Abstract

Incomplete carbonization of sulfoaromatic hydrocarbons results in a carbon material that consists of small polycyclic aromatic carbon sheets with attached SO₃H groups (see picture). This insoluble solid acid exhibits remarkably high activity in the formation of ethyl acetate, the hydrolysis of cyclohexyl acetate, and the hydration of 2,3-dimethyl-2-butene.

Original language	English
Pages (from-to)	2955-2958
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	22
DOIs	https://doi.org/10.1002/anie.200453947
Publication status	Published - May 24 2004
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

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10.1002/anie.200453947

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abstract = "Incomplete carbonization of sulfoaromatic hydrocarbons results in a carbon material that consists of small polycyclic aromatic carbon sheets with attached SO3H groups (see picture). This insoluble solid acid exhibits remarkably high activity in the formation of ethyl acetate, the hydrolysis of cyclohexyl acetate, and the hydration of 2,3-dimethyl-2-butene.",

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author = "Michikazu Hara and Takemi Yoshida and Atsushi Takagaki and Tsuyoshi Takata and Kondo, \{Junko N.\} and Shigenobu Hayashi and Kazunari Domen",

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AU - Yoshida, Takemi

AU - Takagaki, Atsushi

AU - Takata, Tsuyoshi

AU - Kondo, Junko N.

AU - Hayashi, Shigenobu

AU - Domen, Kazunari

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N2 - Incomplete carbonization of sulfoaromatic hydrocarbons results in a carbon material that consists of small polycyclic aromatic carbon sheets with attached SO3H groups (see picture). This insoluble solid acid exhibits remarkably high activity in the formation of ethyl acetate, the hydrolysis of cyclohexyl acetate, and the hydration of 2,3-dimethyl-2-butene.

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KW - Carbon

KW - Heterogeneous catalysis

KW - Protonation

KW - Solid acids

KW - X-ray diffraction

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U2 - 10.1002/anie.200453947

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 22

ER -

A carbon material as a strong protonic acid

Abstract

All Science Journal Classification (ASJC) codes

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