A Bis-[C(trimethylsilyl)-N-arylimino]dimethylsilane, Me 3Si(C= NAr)SiMe 2(C=NAr)SiMe 3 (Ar = 2,6-xylyl), as a New β-Diimine Ligand

Masao Tanabiki; Yusuke Sunada; Hideo Nagashima

doi:10.1021/om700711r

A Bis-[C(trimethylsilyl)-N-arylimino]dimethylsilane, Me ₃Si(C= NAr)SiMe ₂(C=NAr)SiMe ₃ (Ar = 2,6-xylyl), as a New β-Diimine Ligand

Masao Tanabiki, Yusuke Sunada, Hideo Nagashima

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

A cobalt complex having bis-[C(trimethylsilyl)-N-arylimino]dimethylsilane, Me ₃Si(C=NAr)SiMe ₂(C=NAr)SiMe ₃ (Ar = 2,6-xylyl), as a new β-diimine ligand was synthesized, and its structure was compared with those of α- and β-diimine cobalt complexes. Ethylene polymerization catalyzed by these cobalt complexes and their in situ generated nickel homologues was investigated.

Original language	English
Pages (from-to)	6055-6058
Number of pages	4
Journal	Organometallics
Volume	26
Issue number	24
DOIs	https://doi.org/10.1021/om700711r
Publication status	Published - Nov 19 2007

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "A Bis-[C(trimethylsilyl)-N-arylimino]dimethylsilane, Me 3Si(C= NAr)SiMe 2(C=NAr)SiMe 3 (Ar = 2,6-xylyl), as a New β-Diimine Ligand",

abstract = "A cobalt complex having bis-[C(trimethylsilyl)-N-arylimino]dimethylsilane, Me 3Si(C=NAr)SiMe 2(C=NAr)SiMe 3 (Ar = 2,6-xylyl), as a new β-diimine ligand was synthesized, and its structure was compared with those of α- and β-diimine cobalt complexes. Ethylene polymerization catalyzed by these cobalt complexes and their in situ generated nickel homologues was investigated.",

author = "Masao Tanabiki and Yusuke Sunada and Hideo Nagashima",

year = "2007",

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language = "English",

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journal = "Organometallics",

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T1 - A Bis-[C(trimethylsilyl)-N-arylimino]dimethylsilane, Me 3Si(C= NAr)SiMe 2(C=NAr)SiMe 3 (Ar = 2,6-xylyl), as a New β-Diimine Ligand

AU - Tanabiki, Masao

AU - Sunada, Yusuke

AU - Nagashima, Hideo

PY - 2007/11/19

Y1 - 2007/11/19

N2 - A cobalt complex having bis-[C(trimethylsilyl)-N-arylimino]dimethylsilane, Me 3Si(C=NAr)SiMe 2(C=NAr)SiMe 3 (Ar = 2,6-xylyl), as a new β-diimine ligand was synthesized, and its structure was compared with those of α- and β-diimine cobalt complexes. Ethylene polymerization catalyzed by these cobalt complexes and their in situ generated nickel homologues was investigated.

AB - A cobalt complex having bis-[C(trimethylsilyl)-N-arylimino]dimethylsilane, Me 3Si(C=NAr)SiMe 2(C=NAr)SiMe 3 (Ar = 2,6-xylyl), as a new β-diimine ligand was synthesized, and its structure was compared with those of α- and β-diimine cobalt complexes. Ethylene polymerization catalyzed by these cobalt complexes and their in situ generated nickel homologues was investigated.

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U2 - 10.1021/om700711r

DO - 10.1021/om700711r

M3 - Article

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JO - Organometallics

JF - Organometallics

IS - 24

ER -

A Bis-[C(trimethylsilyl)-N-arylimino]dimethylsilane, Me ₃Si(C= NAr)SiMe ₂(C=NAr)SiMe ₃ (Ar = 2,6-xylyl), as a New β-Diimine Ligand

Abstract

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