2,6-Divinylation of phenols with ethyne

Masahiko Yamaguchi; Mieko Arisawa; Yoshiyuki Kido; Masahiro Hirama

doi:10.1039/a704379a

2,6-Divinylation of phenols with ethyne

Masahiko Yamaguchi, Mieko Arisawa, Yoshiyuki Kido, Masahiro Hirama

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Phenols are 2,6-divinylated by treatment with ethyne at 100°C in chlorobenzene in the presence of SnCl₄-Bu₃N, the divinylation occurring predominantly to exclusively with phenol, alkylphenols and alkoxyphenols; an appropriate amount of the tin reagent and the correct reaction temperature are essential for the divinylation.

Original language	English
Pages (from-to)	1663-1664
Number of pages	2
Journal	Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/a704379a
Publication status	Published - 1997
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a704379a

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title = "2,6-Divinylation of phenols with ethyne",

abstract = "Phenols are 2,6-divinylated by treatment with ethyne at 100°C in chlorobenzene in the presence of SnCl4-Bu3N, the divinylation occurring predominantly to exclusively with phenol, alkylphenols and alkoxyphenols; an appropriate amount of the tin reagent and the correct reaction temperature are essential for the divinylation.",

author = "Masahiko Yamaguchi and Mieko Arisawa and Yoshiyuki Kido and Masahiro Hirama",

year = "1997",

doi = "10.1039/a704379a",

language = "English",

pages = "1663--1664",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "17",

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T1 - 2,6-Divinylation of phenols with ethyne

AU - Yamaguchi, Masahiko

AU - Arisawa, Mieko

AU - Kido, Yoshiyuki

AU - Hirama, Masahiro

PY - 1997

Y1 - 1997

N2 - Phenols are 2,6-divinylated by treatment with ethyne at 100°C in chlorobenzene in the presence of SnCl4-Bu3N, the divinylation occurring predominantly to exclusively with phenol, alkylphenols and alkoxyphenols; an appropriate amount of the tin reagent and the correct reaction temperature are essential for the divinylation.

AB - Phenols are 2,6-divinylated by treatment with ethyne at 100°C in chlorobenzene in the presence of SnCl4-Bu3N, the divinylation occurring predominantly to exclusively with phenol, alkylphenols and alkoxyphenols; an appropriate amount of the tin reagent and the correct reaction temperature are essential for the divinylation.

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U2 - 10.1039/a704379a

DO - 10.1039/a704379a

M3 - Article

AN - SCOPUS:1542685254

SN - 1359-7345

SP - 1663

EP - 1664

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

2,6-Divinylation of phenols with ethyne

Abstract

All Science Journal Classification (ASJC) codes

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