(2,2′-Bipyridine)bis(N-methyl-4,4′-bi-pyridinium)platinum(II) tetraperchlorate

Ken Sakai; Manabu Osada; Yoshimi Yokoyama; Yasushi Tomita; Taro Tsubomura

doi:10.1107/S1600536803013801

(2,2′-Bipyridine)bis(N-methyl-4,4′-bi-pyridinium)platinum(II) tetraperchlorate

Ken Sakai, Manabu Osada, Yoshimi Yokoyama, Yasushi Tomita, Taro Tsubomura

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

In the title compound, [Pt(C₁₀H₈N₂)(C ₁₁H₁₁N₂)₂](ClO₄) ₄, the square-planar PtN₄ coordination geometry is slightly deformed, with the coordinated N atom of one of the N-methyl-4,4′-bipyridinium (MQ) ligands 0.262 (8) Å out of the plane defined by the rest of the coordinated N atoms and the Pt atom. The exceptional behavior of this MQ ligand is interpreted in terms of the electrostatic interactions between the positively charged MQ ligands and the perchlorate anions, where the N(MQ)⋯O(perchlorate) distances are in the range 2.932 (12)-3.259 (13) Å.

Original language	English
Pages (from-to)	m512-m514
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	7
DOIs	https://doi.org/10.1107/S1600536803013801
Publication status	Published - Jul 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1107/S1600536803013801

Cite this

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title = "(2,2′-Bipyridine)bis(N-methyl-4,4′-bi-pyridinium)platinum(II) tetraperchlorate",

abstract = "In the title compound, [Pt(C10H8N2)(C 11H11N2)2](ClO4) 4, the square-planar PtN4 coordination geometry is slightly deformed, with the coordinated N atom of one of the N-methyl-4,4′-bipyridinium (MQ) ligands 0.262 (8) {\AA} out of the plane defined by the rest of the coordinated N atoms and the Pt atom. The exceptional behavior of this MQ ligand is interpreted in terms of the electrostatic interactions between the positively charged MQ ligands and the perchlorate anions, where the N(MQ)⋯O(perchlorate) distances are in the range 2.932 (12)-3.259 (13) {\AA}.",

author = "Ken Sakai and Manabu Osada and Yoshimi Yokoyama and Yasushi Tomita and Taro Tsubomura",

year = "2003",

month = jul,

doi = "10.1107/S1600536803013801",

language = "English",

volume = "59",

pages = "m512--m514",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "7",

}

TY - JOUR

T1 - (2,2′-Bipyridine)bis(N-methyl-4,4′-bi-pyridinium)platinum(II) tetraperchlorate

AU - Sakai, Ken

AU - Osada, Manabu

AU - Yokoyama, Yoshimi

AU - Tomita, Yasushi

AU - Tsubomura, Taro

PY - 2003/7

Y1 - 2003/7

N2 - In the title compound, [Pt(C10H8N2)(C 11H11N2)2](ClO4) 4, the square-planar PtN4 coordination geometry is slightly deformed, with the coordinated N atom of one of the N-methyl-4,4′-bipyridinium (MQ) ligands 0.262 (8) Å out of the plane defined by the rest of the coordinated N atoms and the Pt atom. The exceptional behavior of this MQ ligand is interpreted in terms of the electrostatic interactions between the positively charged MQ ligands and the perchlorate anions, where the N(MQ)⋯O(perchlorate) distances are in the range 2.932 (12)-3.259 (13) Å.

AB - In the title compound, [Pt(C10H8N2)(C 11H11N2)2](ClO4) 4, the square-planar PtN4 coordination geometry is slightly deformed, with the coordinated N atom of one of the N-methyl-4,4′-bipyridinium (MQ) ligands 0.262 (8) Å out of the plane defined by the rest of the coordinated N atoms and the Pt atom. The exceptional behavior of this MQ ligand is interpreted in terms of the electrostatic interactions between the positively charged MQ ligands and the perchlorate anions, where the N(MQ)⋯O(perchlorate) distances are in the range 2.932 (12)-3.259 (13) Å.

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JO - Acta Crystallographica Section E: Structure Reports Online

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IS - 7

ER -

(2,2′-Bipyridine)bis(N-methyl-4,4′-bi-pyridinium)platinum(II) tetraperchlorate

Abstract

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