1,4-Remote stereocontrol via asymmetric [2,3]-Wittig rearrangements

Katsuhiko Tomooka; Ping Huai Keong; Takeshi Nakai

doi:10.1016/0040-4039(95)00397-U

1,4-Remote stereocontrol via asymmetric [2,3]-Wittig rearrangements

Katsuhiko Tomooka, Ping Huai Keong, Takeshi Nakai

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The carbanion rearrangement of the propargylic ether of the β-(1-alkoxyethyl) allyl alcohol was found to proceed with a high degree of either 1,4-syn or 1,4-anti selection by virtue of the proper choice of the combination of the alkoxy group with the solvent used.

Original language	English
Pages (from-to)	2789-2792
Number of pages	4
Journal	Tetrahedron Letters
Volume	36
Issue number	16
DOIs	https://doi.org/10.1016/0040-4039(95)00397-U
Publication status	Published - Apr 17 1995
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/0040-4039(95)00397-U

Cite this

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title = "1,4-Remote stereocontrol via asymmetric [2,3]-Wittig rearrangements",

abstract = "The carbanion rearrangement of the propargylic ether of the β-(1-alkoxyethyl) allyl alcohol was found to proceed with a high degree of either 1,4-syn or 1,4-anti selection by virtue of the proper choice of the combination of the alkoxy group with the solvent used.",

author = "Katsuhiko Tomooka and Keong, {Ping Huai} and Takeshi Nakai",

year = "1995",

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day = "17",

doi = "10.1016/0040-4039(95)00397-U",

language = "English",

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T1 - 1,4-Remote stereocontrol via asymmetric [2,3]-Wittig rearrangements

AU - Tomooka, Katsuhiko

AU - Keong, Ping Huai

AU - Nakai, Takeshi

PY - 1995/4/17

Y1 - 1995/4/17

N2 - The carbanion rearrangement of the propargylic ether of the β-(1-alkoxyethyl) allyl alcohol was found to proceed with a high degree of either 1,4-syn or 1,4-anti selection by virtue of the proper choice of the combination of the alkoxy group with the solvent used.

AB - The carbanion rearrangement of the propargylic ether of the β-(1-alkoxyethyl) allyl alcohol was found to proceed with a high degree of either 1,4-syn or 1,4-anti selection by virtue of the proper choice of the combination of the alkoxy group with the solvent used.

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U2 - 10.1016/0040-4039(95)00397-U

DO - 10.1016/0040-4039(95)00397-U

M3 - Article

AN - SCOPUS:0028901188

SN - 0040-4039

VL - 36

SP - 2789

EP - 2792

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 16

ER -

1,4-Remote stereocontrol via asymmetric [2,3]-Wittig rearrangements

Abstract

All Science Journal Classification (ASJC) codes

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