(η5-C5Me5)Ru(amidinate): Highly Reactive Ruthenium Complexes Formally Bearing 16 Valence Electrons Showing Signs of Coordinative Unsaturation

Yoshitaka Yamaguchi; Hideo Nagashima

doi:10.1021/om990872d

(η⁵-C₅Me₅)Ru(amidinate): Highly Reactive Ruthenium Complexes Formally Bearing 16 Valence Electrons Showing Signs of Coordinative Unsaturation

Yoshitaka Yamaguchi, Hideo Nagashima

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

71 Citations (Scopus)

Abstract

Novel coordinatively unsaturated ruthenium complexes, (η⁵-C₅Me₅)Ru(amidinate), were synthesized from [(η⁵-C₅Me₅)Ru(OMe)]₂ and lithium amidinates, which exist as monomers in both solution and solid states and are highly reactive toward two-electron ligands.

Original language	English
Pages (from-to)	725-726
Number of pages	2
Journal	Organometallics
Volume	19
Issue number	5
DOIs	https://doi.org/10.1021/om990872d
Publication status	Published - Mar 6 2000

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om990872d

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title = "(η5-C5Me5)Ru(amidinate): Highly Reactive Ruthenium Complexes Formally Bearing 16 Valence Electrons Showing Signs of Coordinative Unsaturation",

abstract = "Novel coordinatively unsaturated ruthenium complexes, (η5-C5Me5)Ru(amidinate), were synthesized from [(η5-C5Me5)Ru(OMe)]2 and lithium amidinates, which exist as monomers in both solution and solid states and are highly reactive toward two-electron ligands.",

author = "Yoshitaka Yamaguchi and Hideo Nagashima",

year = "2000",

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doi = "10.1021/om990872d",

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AU - Nagashima, Hideo

PY - 2000/3/6

Y1 - 2000/3/6

N2 - Novel coordinatively unsaturated ruthenium complexes, (η5-C5Me5)Ru(amidinate), were synthesized from [(η5-C5Me5)Ru(OMe)]2 and lithium amidinates, which exist as monomers in both solution and solid states and are highly reactive toward two-electron ligands.

AB - Novel coordinatively unsaturated ruthenium complexes, (η5-C5Me5)Ru(amidinate), were synthesized from [(η5-C5Me5)Ru(OMe)]2 and lithium amidinates, which exist as monomers in both solution and solid states and are highly reactive toward two-electron ligands.

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(η⁵-C₅Me₅)Ru(amidinate): Highly Reactive Ruthenium Complexes Formally Bearing 16 Valence Electrons Showing Signs of Coordinative Unsaturation

Abstract

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